Development of HCl-free solid phase extraction combined with ICP-MS/MS for rapid assessment of difficult-to-measure radionuclides, 2; Highly sensitive monitoring of Sn in concrete rubble

Do, V. K.; Furuse, Takahiro; Ota, Yuki; Iwahashi, Hiroyuki; Hirosawa, Takashi; Watanabe, Masahisa; Sato, Soichi

Journal of Radioanalytical and Nuclear Chemistry, 331(12), p.5631 - 5640, 2022/12

https://doi.org/10.1007/s10967-022-08612-7

Sn is one of the long-lived fission products that might have been released into the environment after the Fukushima nuclear accident in Japan in 2011. The presence of radionuclides must be monitored for the proper treatment of wastes obtained from decommissioning accident-related nuclear facilities and the surrounding environment. In the work, we propose a reliable method for verifying the presence of Sn in construction materials by combining the HCl-free solid phase extraction on TEVA resin and a selective measurement by inductively coupled plasma tandem mass spectrometry (ICP-MS/MS). The method has been optimized and characterized step by step. More than 95% of chemical recovery was achieved for Sn from typical concrete matrixes. The interference caused by an isobar Te and possible polyatomic interferences from matrixes were effectively suppressed by the developed chemical separation and the tandem MS/MS configuration. The total decontamination factor for the Te interference was of the order of 10. The estimated method detection limit for Sn in concrete as measured at m/z = 160 was 12.1 pg g, which is equivalent to 6.1 mBq g.

Angular distribution of rays from the -wave resonance of Sn

Koga, Jun*; Takada, Shusuke*; Endo, Shunsuke; Fujioka, Hiroyuki*; Hirota, Katsuya*; Ishizaki, Kohei*; Kimura, Atsushi; Kitaguchi, Masaaki*; Niinomi, Yudai*; Okudaira, Takuya*; et al.

Physical Review C, 105(5), p.054615_1 - 054615_5, 2022/05

https://doi.org/10.1103/PhysRevC.105.054615

no abstracts in English

Development of neutron transport calculation codes for 3-D hexagonal geometry, 2; Improvement and enhancement of the MINISTRI code

Sugino, Kazuteru; Takino, Kazuo

JAEA-Data/Code 2019-011, 110 Pages, 2020/01

JAEA-Data-Code-2019-011.pdf:3.37MB

A deterministic discrete ordinates method (SN method) transport calculation code for three-dimensional hexagonal geometry has been developed as the MINISTRI code (Ver. 7.0). MINISTRI is based on the triangle-mesh finite difference method, which can perform neutron transport calculations with high accuracy for cores of fast power reactors and assemblies of the Russian BFS critical facility. The present study has derived a proper scheme for remarkably improving the convergence of MINISTRI by investigating the issue of previous MINISTRI (Ver. 1.1), which sometimes plays a poor convergence performance in calculations for large-scale power reactor cores. The verification test of improved MINISTRI has been carried out for various cores by setting the reference result as the multi-group Monte-Carlo calculation with the same cross-sections as used in MINISTRI. As a result, it is found that the agreements are within 0.1% for eigenvalues and within 0.7% for power distributions. Thus, the satisfying accuracy of MINISTRI has been confirmed. In order to reduce the calculation time, the initial diffusion calculation scheme and the parallel processing have been implemented. As a result, the calculation time is reduced to the approximately one tenth compared with previous MINISTRI. Furthermore, adoption of the treatment of the anisotropic cell streaming effect, preparation of the perturbation calculation tool, implementation of the function for specification of the triangle-mesh-wise material and merging of the hexagonal-mesh calculation code MINIHEX have been carried out. Thus, the versatility of MINISTRI has been enhanced.

Study for estimation of snow depth by using DSM made by SfM method

Miyasaka, Satoshi*; Unome, Sota*; Tamura, Ayako*; Ito, Yoshiaki*; Ishizaki, Azusa; Sanada, Yukihisa

Nihon Rimoto Senshingu Gakkai Dai-63-Kai (Heisei-29-Nendo Shuki) Gakujutsu Koenkai Rombunshu (CD-ROM), p.81 - 84, 2017/11

Information of snow depth is important to improve the airborne radiation measurement in the winter. The snow depth is enable to estimate by the aerial photograph which is obtained at the same time with the radiation measurement before and after the snowfall. We attempted optimization parameters which used to make a Digital Surface Model (DSM) using Structure from Motion (SfM) method for estimation of the snow depth. As a result, to enable to measure precisely the snow depth was indicated. However, the estimated snow depth in the forest area was relatively not so accurate because fallen leaves and a tree move were prevented to measure DSM precisely.

Development of probabilistic risk assessment methodology against extreme snow for sodium-cooled fast reactor

Yamano, Hidemasa; Nishino, Hiroyuki; Kurisaka, Kenichi

Nuclear Engineering and Design, 308, p.86 - 95, 2016/11

https://doi.org/10.1016/j.nucengdes.2016.08.006

This paper describes snow probabilistic risk assessment (PRA) methodology development through external hazard and event sequence evaluations mainly in terms of decay heat removal (DHR) function of a sodium-cooled fast reactor (SFR). Using recent 50-year weather data at a typical Japanese SFR site, snow hazard categories were set for the combination of daily snowfall depth (snowfall speed) and snowfall duration which can be calculated by dividing the snow depth by the snowfall speed. For each snow hazard category, the event sequence was evaluated by event trees which consist of several headings representing the loss of DHR. Snow removal action and manual operation of the air cooler dampers were introduced into the event trees as accident managements. Access route failure probability model was also developed for the quantification of the event tree. In this paper, the snow PRA showed less than 10/reactor-year of core damage frequency. The dominant snow hazard category was the combination of 1-2 m/day of snowfall speed and 0.5-0.75 day of snowfall duration. Importance and sensitivity analyses indicated a high risk contribution to secure the access routes.

Spontaneous activation behavior of NiSn, an intermetallic catalyst, for hydrogen production via methanol decomposition

Fan, M.*; Xu, Y.*; Sakurai, Junya*; Demura, Masahiko*; Hirano, Toshiyuki*; Teraoka, Yuden; Yoshigoe, Akitaka

International Journal of Hydrogen Energy, 40(37), p.12663 - 12673, 2015/10

https://doi.org/10.1016/j.ijhydene.2015.05.197

The catalytic properties of single-phase NiSn powder in the production of hydrogen via the decomposition of methanol were investigated in isothermal tests at 713, 793, and 873 K. The catalytic activity of NiSn significantly increased with time at 793 and 873 K, but not at 713 K, suggesting that NiSn is spontaneously activated at temperatures above 793 K. At these temperatures, NiSn showed high selectivity for H and CO production and low selectivity for CH, CO, and HO production, indicating that methanol decomposition was the main reaction, and that side reactions such as methanation and water-gas shift reaction were suppressed. Surface analysis revealed that fine NiSn particles were formed during the reaction, accompanied by a small amount of deposited carbon. The formation of these particles was suggested to be the cause for the spontaneous activation of NiSn.

Development of risk assessment methodology of decay heat removal function against external hazards for sodium-cooled fast reactors, 1; Project overview and margin assessment methodology against snow

Yamano, Hidemasa; Nishino, Hiroyuki; Kurisaka, Kenichi; Okano, Yasushi; Sakai, Takaaki; Yamamoto, Takahiro*; Ishizuka, Yoshihiro*; Geshi, Nobuo*; Furukawa, Ryuta*; Nanayama, Futoshi*; et al.

Proceedings of 23rd International Conference on Nuclear Engineering (ICONE-23) (DVD-ROM), 10 Pages, 2015/05

This paper describes mainly snow margin assessment methodology development in addition to the project overview. For the snow margin assessment, the index is a combination of a snowfall rate and duration. Since snow removal can be expected during the snowfall, the developed snow margin assessment methodology is such that the margin was regarded as the snowfall duration up to the decay heat removal failure which was defined as when the snow removal rate was smaller than the snowfall rate.

Structural analysis of Ge(111)-33-Sn surface at low-temperature by reflection high-energy positron diffraction

Fukaya, Yuki; Kawasuso, Atsuo; Ichimiya, Ayahiko

Surface Science, 600(18), p.4086 - 4088, 2006/09

https://doi.org/10.1016/j.susc.2005.11.069

no abstracts in English

A New model to simulate critical current degradation of a large CICC by taking into account strand bending

Koizumi, Norikiyo; Nunoya, Yoshihiko; Okuno, Kiyoshi

IEEE Transactions on Applied Superconductivity, 16(2), p.831 - 834, 2006/06

https://doi.org/10.1109/TASC.2005.869640

no abstracts in English

Design of "NeutrOn Beam-line for Observation & Research Use (NOBORU)" for JSNS of J-PARC

Maekawa, Fujio; Oikawa, Kenichi; Tamura, Masaya; Harada, Masahide; Ikeda, Yujiro; Watanabe, Noboru

LA-UR-06-3904, Vol.1, p.129 - 138, 2006/06

Total 23 neutron beam-lines will be installed for JSNS in the J-PARC project. One of them is assigned for the Materials and Life Science Facility (MLF), and the MLF will construct a neutron beam-line to demonstrate and monitor neutronic performance of JSNS. The neutron beam-line was accordingly named as "Neutron Beam-line for Obserbation and Research Use (NOBORU)". Major parts of the NOBORU, i.e., beam ducts, shield, a beam stop, slits, a cabin for measurement, a pillar crane, a sample table, etc., have been ordered in March 2004, and installation will be completed in 2007. A T0 chopper, a frame-overlap chopper, detector systems, samples, etc. will be ordered later on. The sample position is at 14 m from the decoupled moderator. Approximate sample room dimensions are 3 2.5 m in area and 3 m in height. A shield structure was determined by shielding calculations in which detailed 3-D structure was considered. The design of NOBORU will be presented in the session.